(1983) Preparation of Sodium Zirconium Phosphates of the Type Na 1+4xZr 2−x(PO 4) 3. May GJ, Hooper A (1978) The effect of microstructure and phase composition on the ionic conductivity of magnesium-doped sodium-beta-alumina. (2015) Low temperature performance of sodium–nickel chloride batteries with NaSICON solid electrolyte. Goodenough JB, Hong HYP, Kafalas JA (1976) Fast Na +-Ion Transport in Skeleton Structures. Hong HYP (1976) Crystal Structure and Crystal Chemistry in the System Na 1+xZr 2Si xP 3−xO 12. (2010) Advanced materials for sodium-beta alumina batteries: Status, challenges and perspectives. (2015) Sodium nickel chloride battery technology for large-scale stationary storage in the high voltage network. Electrochem Soc Interface 19: 49–53.īenato R, Cosciani N, Crugnola G, et al. (2010) Batteries for Large-Scale Stationary Electrical Energy Storage. Nat Chem 7: 19–29.ĭoughty DH, Butler PC, Akhil AA, et al. Larcher D, Tarascon JM (2015) Towards greener and more sustainable batteries for electrical energy storage. Phase relations of NASICON materials and compilation of the quaternary phase diagram Na2O-P2O5-SiO2-ZrO2. The implications of the formation of secondary phases and glass-ceramic composites are discussed in terms of technological applications.Ĭitation: Frank Tietz. The three-dimensional representation also better elucidates the regions connecting the edges of the NASICON tetrahedron with ternary and binary compounds as well as single oxides, i.e., ZrO 2 and ZrSiO 4, Na 3PO 4, sodium silicates and sodium zirconium silicates and gives a better understanding of phase formations during the processing of the ceramics. However, the three-dimensional presentation clearly elucidates that few reported compositions exist outside this compressed tetrahedron indicating that the phase region of NASICON materials may be larger than the solid solutions known so far. To date, the NASICON region can be described as a compressed tetrahedron within the tetrahedral phase diagram. On the basis of published data the three-dimensional phase region of NASICON materials is constructed and phase relations to ternary and binary systems as well as to single oxides are presented. Maguire, Rachael L.A short overview is given on existing phase relations in the four related ternary diagrams, setting the frame for a quaternary phase diagram. This simulation was made at the University of Colorado Boulder, Department of Chemical and Biological Engineering.
![two phase region ternary diagram two phase region ternary diagram](https://files.transtutors.com/book/qimg/834e50bb-fa03-4886-bd20-afdfd5f0a9cd.png)
Two phase region ternary diagram free#
This simulation runs on desktop using the free Wolfram Player. Ternary phase diagrams can also be drawn using mole fractions instead of mass fractions. The fraction of the distance from the base to the corner is the mass fraction of that component. In the “alternate view”, the mass fraction of a component is determined by drawing a line through the point and perpendicular to the base opposite that component. These axes are labeled by drawing a line through the point this line is parallel to the base of the triangle that is opposite the corner corresponding to that pure component. The mass fraction of a component in the mixture is read off the axis that is the same color as that component in the standard view. Each corner of the triangle corresponds to a pure component. Move the black dot to any location within the triangle by clicking on that location, which represents the overall composition of the mixture. This simulation shows two representations of a ternary phase diagram, which is used to represent the phase behavior of three-component mixtures.